I don’t know what chain reaction exactly they were thinking of, but from modern fusion research, I believe we can confidently say that the atmosphere would need to be interior-of-a-large-star-level dense, and even then I’m not sure you’d get nitrogen fusing with anything without a lot of hydrogen or helium around. Nitrogen-nitrogen fusion seems extremely implausible for sure
I took “rather than the other way around” to mean “rather than negatively-correlated” in this context, since positively was emphasized